Penerapan Model Matematika pada Kinetika Reaksi Oksidasi Fero Sulfat Menjadi Feri Sulfat dengan Katalis Kupri Sulfat

Neneng Purnamawat, Leo Adhar Effendi

Abstract


Oxidation of ferrous sulphate to ferric sulphate was conducted in an agitated reactor using cupri
sulphate as catalyst. This experiment was performed at ferrous sulphate initial concentration of 0.4 N,
reaction temperature of 40-90 C, agitator speed of 220-400 rpm, volumetric rate of gas of 31.94-61.56
mL/s. Mass transfer coefficient and reaction rate constant were calculated by using Runge-Kutta and
Hooke-Jeeves method.
Based on the experimentally result, the value of maximum conversion obtained was 30.71% at
reaction temperature of 70 C, agitator speed of 290 rpm, and volumetric rate of gas of 40.26 mL/s.
Evaluation of mass transfer coefficient and reaction rate constant revealed that the step of controlling the
overall process is chemical reaction.

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References


Fogler, H., S., 1999, “Elements of Chemical Reaction Engineering”, 3rd ed., Prentice-Hall

International, Inc., New Jersey.

Jenson, V.G., Jeffreys, G.V., 1977, “Mathematical Methods in Chemical Engineering”, 2nd ed,

Academic Press, Inc., New York.

Levenspiel, O., 1999, “Chemical Reaction Engineering”, 3rd ed, John Wiley & Sons, New York.

Perry, RH., Green, D.W., and Maloney, J.D., 1984, “Chemical Engineers Handbook”, 6th ed, pp 3-

, McGraw Hill International Book Company, Inc., Toronto.

Ronnholm, M.R., Warna, J., Salmi, T., Turunen, I., Luoma, M, 1999, ”Kinetics of Oxidation of

Ferrous Sulfate with Molecular Oxygen”, Chem. Eng. Sci., 54, 4223 - 4232.

Ronnholm, M.R., Warna, J., Salmi, T., 2002, ”Two-and three-phase Oxidation od Ferrous Sulfate to

Ferric Sulfate from Intrinsic Kinetics to Diffusion-affected Industrial Kinetics”, Chem. Eng. And

Processing., 41, 753 - 760.

Sediawan W.B, Prasetya A., 1997, “Pemodelan Matematis dan Penyelesaian Numeris dalam

Teknik Kimia”, ANDI, Yogyakarta.


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